1-Chloro-2, 4-dinitroanthraquinone

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1,10-Phenanthrolinium 4-chloro-2-hydroxy­benzoate–1,10-phenanthroline–4-chloro-2-hydroxy­benzoic acid (1/1/1)

The title compound, C(12)H(9)N(2) (+)·C(7)H(4)ClO(3) (-)·C(12)H(8)N(2)·C(7)H(5)ClO(3), contains one phenanthrolinium (Hphen) cation, one phenanthroline (phen) mol-ecule, one 4-chloro-2-hydroxy-benzoate anion (hcba) and one 4-chloro-2-hydroxy-benzoic acid (Hhcba) mol-ecule in the asymmetric unit. The phen mol-ecule is approximately parallel to Hphen, making a dihedral angle of 1.98 (6)°. The cen...

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4-Chloro-1-iodo-2-nitro­benzene

In the mol-ecule of the title compound, C(6)H(3)ClINO(2), the nitro group is disordered over two sites with occupancies of 0.506 (6) and 0.494 (6). The dihedral angles between the benzene ring and the two disordered components of the nitro group are 29.0 (2) and 51.0 (3)°. The disordering avoids short O⋯O inter-molecular contacts in the crystal.

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2-Chloro-1-(4-hy­droxy­phen­yl)ethanone

The asymmetric unit of the title compound, C(8)H(7)ClO(2), consists of two independent mol-ecules, with comparable geometries. Both mol-ecules are approximately planar (r.m.s. deviations = 0.040 and 0.064 Å for the 11 non-H atoms). In the crystal, mol-ecules are linked via inter-molecular O-H⋯O and C-H⋯O hydrogen bonds into chains two mol-ecules thick along (-101).

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2-Chloro-4-(3,3-dichloro­all­yloxy)-1-nitro­benzene

In the crystal structure of the title compound, C(9)H(6)Cl(3)NO(3), mol-ecules are connected by C-H⋯O hydrogen bonds, forming chains along the b axis. The dihedral angle between the benzene ring and the plane of the nitro group is 16.2 (1)° and that between the benzene ring and the plane of the dichloro-allyl group is 10.2 (1)°.

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2-Chloro-1-(3-fluoro­benz­yloxy)-4-nitro­benzene

In the title compound, C(13)H(9)ClFNO(3), the benzene rings are oriented at a dihedral angle of 41.23 (5)°. In the crystal structure, inter-molecular C-H⋯O inter-actions link the mol-ecules in a herring-bone arrangement along the b axis and weak π-π contacts between the benzene rings [centroid-centroid distance = 3.881 (1) Å] may further stabilize the structure.

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ژورنال

عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan

سال: 1953

ISSN: 0037-9980,1883-6526

DOI: 10.5059/yukigoseikyokaishi.11.469